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404926

Sigma-Aldrich

Vanadium(V) oxytriisopropoxide

Synonym(s):

Triisopropoxyvanadium(V) oxide, VTIP, Vanadium(V) trisisopropoxide oxide

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About This Item

Linear Formula:
OV(OCH(CH3)2)3
CAS Number:
Molecular Weight:
244.20
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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form

liquid

Quality Level

composition

V, 20.3-21.4% titration (, by potassium permanganate)

reaction suitability

core: vanadium
reagent type: catalyst

refractive index

n20/D 1.479 (lit.)

bp

80-82 °C/2 mmHg (lit.)

density

1.035 g/mL at 25 °C (lit.)

SMILES string

CC(C)O[V](=O)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3

InChI key

DSGGJXAUQHKOGQ-UHFFFAOYSA-N

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Application

Vanadium(V) oxytriisopropoxide is a building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis. Vanadium (V) oxytriisopropoxide (VOTP) may be used directly as a V precursor to dope TiO2 to form a high performance anode for lithium ion batteries.

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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