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451622

Sigma-Aldrich

Lithium tetrafluoroborate

greener alternative

ultra dry, powder, 99.99% trace metals basis

Synonym(s):

Lithium borofluoride, Lithium fluoroborate

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About This Item

Linear Formula:
LiBF4
CAS Number:
14283-07-9
Molecular Weight:
93.75
EC Number:
238-178-9
MDL number:
MFCD00011087
UNSPSC Code:
12352302
PubChem Substance ID:
24868639
NACRES:
NA.23
assay:
99.99% trace metals basis
form:
powder

description

Grade: ultra dry

Quality Level

200

assay

99.99% trace metals basis

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤150.0 ppm Trace Metal Analysis

mp

293-300 °C (dec.) (lit.)

greener alternative category

, Enabling

SMILES string

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

InChI key

UFXJWFBILHTTET-UHFFFAOYSA-N

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General description

Lithium tetrafluoroborate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
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Application

LiBF4 is majorly used as an electrolyte with good ionic conductivity. It facilitates the formation of an electrolytic solution or a liquid electrolyte, which can be used in the fabrication of lithium-ion batteries and solid-state electrochemical displays.
Used recently in the development of a solid composite electrolyte for lithium batteries.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ8580
MKCQ1191
MKCM5192
MKCM8671
MKCK7601

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Application of di-ureasil ormolytes based on lithium tetrafluoroborate in solid-state electrochromic displays
Barbosa P, et al.
Journal of Materials Chemistry, 20(4), 723-730 (2010)
Zachary T Gossage et al.
The Analyst, 145(7), 2631-2638 (2020-02-27)
Interphases formed at battery electrodes are key to enabling energy dense charge storage by acting as protection layers and gatekeeping ion flux into and out of the electrodes. However, our current understanding of these structures and how to control their
A new lithium salt with dihydroxybenzene and lithium tetrafluoroborate for lithium battery electrolytes
Xue Z, et al.
Journal of Power Sources, 196(20), 8710-8713 (2011)
Proc. Power Sources Conf., 37th, 287-287 (1996)
Takahiro Ichikawa et al.
Journal of the American Chemical Society, 133(7), 2163-2169 (2011-01-29)
Thermotropic bicontinuous cubic (Cub(bi)) liquid-crystalline (LC) compounds based on a polymerizable ammonium moiety complexed with a lithium salt have been designed to obtain lithium ion-conductive all solid polymeric films having 3D interconnected ionic channels. The monomer shows a Cub(bi) phase
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