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588466

Sigma-Aldrich

Methyl α-bromoacrylate

95%

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About This Item

Empirical Formula (Hill Notation):
C4H5BrO2
CAS Number:
Molecular Weight:
164.99
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Pricing and availability is not currently available.

Quality Level

assay

95%

bp

70-75 °C/48 mmHg (lit.)

density

1.556 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

COC(=O)C(Br)=C

InChI

1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3

InChI key

HVJXPDPGPORYKY-UHFFFAOYSA-N

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This Item
HPA031235HPA037826HPA040411
antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

biological source

rabbit

biological source

rabbit

biological source

rabbit

biological source

rabbit

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

product line

Prestige Antibodies® Powered by Atlas Antibodies

product line

Prestige Antibodies® Powered by Atlas Antibodies

product line

Prestige Antibodies® Powered by Atlas Antibodies

product line

Prestige Antibodies® Powered by Atlas Antibodies

UniProt accession no.

Q8NFP4

UniProt accession no.

Q8NFP4

UniProt accession no.

Q9BT17

UniProt accession no.

Q8TC05

Application

Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. [1] Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. [2] It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity.[3] These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates. [4]

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

134.6 °F - closed cup

flash_point_c

57 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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    Copolymerizations of methyl ?-bromoacrylate, 2-bromoethyl methacrylate and 2,3-dibromopropyl methacrylate with vinyltriacetoxysilane
    Rao VL and Babu GN
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