591971

Poly(2,2,3,3,4,4,4-heptafluorobutyl methacrylate)

• Linear Formula: (C₈H₇F₇O₂)_n
• MDL number: MFCD04975230
• UNSPSC Code: 12352103
• NACRES: NA.23

Properties

• form: solid
• refractive index: n20/D 1.383 (lit.)
• transition temp: T_g (DSC) 65 °C
• solubility: DMSO: soluble; NMP: soluble; THF: soluble; methylene chloride: slightly soluble

Description

Application

Low refractive index polymer for cladding layer in optical waveguides. Transparent, low surface tension polymer.

Poly(2,2,3,3,4,4,4-heptafluorobutyl methacrylate) is a fluorinated polymer used to develop low refractive index optical materials and various optoelectronics including organic photovoltaics, organic field-effect transistors (OFETs), and polymer light-emitting diodes because of its high mechanical strength, high thermal stability, chemical inertness, low dielectric constants, and low water absorptivity.
It is also used to prepare poly[2-(N-carbazolyl)ethyl methacrylate]-block-poly[(2,2,3,3,4,4,4-heptafluorobutyl methacrylate)] (CbzEMAx-b-HFBMAy) diblock copolymers by reversible addition-fragmentation chain transfer (RAFT) polymerization. The availability of a low-surface-energy fluorinated block and an electro-active carbazole fragment in diblock copolymers confers crucial properties for the fabrication of high-quality and high-performance functional thin films.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)