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692972

Sigma-Aldrich

(S)-RuCl[(p-cymene(BINAP)]Cl

Synonym(s):

Chloro[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′−binaphthyl](p-cymene)ruthenium(II) chloride

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About This Item

Linear Formula:
[C54H46ClP2Ru]+Cl-
CAS Number:
130004-33-0
Molecular Weight:
928.87
MDL number:
MFCD00134456
UNSPSC Code:
12352005
PubChem Substance ID:
329761547
NACRES:
NA.22
Pricing and availability is not currently available.

form

powder

Quality Level

100

functional group

phosphine

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.CC(C)c1ccc(C)cc1.c2ccc(cc2)P(c3ccccc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9

InChI

1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

WNHLGYRPKARUHY-UHFFFAOYSA-L

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assay

98%

assay

97%

assay

97%

assay

98%

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

refractive index

n20/D 1.489 (lit.)

refractive index

n20/D 1.509 (lit.)

refractive index

-

refractive index

-

bp

72-75 °C/8 mmHg (lit.)

bp

111-112 °C/18 mmHg (lit.)

bp

-

bp

-

density

1.043 g/mL at 25 °C (lit.)

density

1.078 g/mL at 25 °C (lit.)

density

-

density

-

form

liquid

form

liquid

form

-

form

-

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

  • Specification Sheet

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    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCB6454
    MKBV1438V
    MKBJ9609V
    07196LJV
    07196LJ

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    Articles

    Takasago Ligands

    Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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