701718

2-Azaadamantane-N-oxyl

90%

• Synonym(s): AZADO
• Empirical Formula (Hill Notation): C₉H₁₄NO
• CAS Number: 57625-08-8
• Molecular Weight: 152.21
• MDL number: MFCD11656077
• UNSPSC Code: 12352000
• PubChem Substance ID: 329762314
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 90%
• form: powder
• reaction suitability: reagent type: oxidant
• mp: 182-189 °C (D)
• storage temp.: 2-8°C
• SMILES string: [O]N1[C@@H]2C[C@H]3C[C@@H](C2)C[C@@H]1C3
• InChI: 1S/C9H14NO/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+
• InChI key: BCJCJALHNXSXKE-SPJNRGJMSA-N

Description

General description

2-Azaadamantane-N-oxyl (AZADO), a stable nitroxyl radical, is widely employed as catalyst for the oxidation of alcohols.

Application

2-Azaadamantane-N-oxyl (AZADO) may be employed in the following studies:

• As catalyst for the oxidation of wood cellulose.
• As catalyst in the total synthesis of Yaku′amide A, a potential cytotoxin obtained from sponge Ceratopsion sp.
• As oxidant for the oxidation of (S)-glycidol.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves