750190
Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)
95%
Synonym(s):
Pd-117
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About This Item
Empirical Formula (Hill Notation):
C36H28Cl2OP2Pd
CAS Number:
Molecular Weight:
715.88
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
95%
form
powder
mp
243-250 °C
storage temp.
2-8°C
SMILES string
Cl[Pd]Cl.O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
InChI
1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;;;/h1-28H;2*1H;/q;;;+2/p-2
InChI key
VYOUBMJFTDMKRR-UHFFFAOYSA-L
Related Categories
General description
Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is a palladium(II) complex containing two chloride ligands and two (2-(diphenylphosphino)phenyl)ether ligands coordinated to the palladium center. It is used as a catalyst for the cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z, E dienes.
Application
Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is used as an efficient catalyst in the coupling reaction.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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