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764639

Sigma-Aldrich

5,5′′′-Bis(tridecafluorohexyl)-2,2′:5′,2 ′′:5′′,2′′′-quaterthiophene

Synonym(s):

α,ω-Diperfluorohexyl-quarterthiophene, DFH-4T

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About This Item

Empirical Formula (Hill Notation):
C28H8F26S4
CAS Number:
446043-85-2
Molecular Weight:
966.58
MDL number:
MFCD23098728
UNSPSC Code:
12352103
PubChem Substance ID:
329767133
NACRES:
NA.23
Pricing and availability is not currently available.

form

solid

Quality Level

100

mp

205-210 °C

semiconductor properties

N-type (mobility≤0.64 cm2/V·s)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c1ccc(s1)-c2ccc(s2)-c3ccc(s3)-c4ccc(s4)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C28H8F26S4/c29-17(30,19(33,34)21(37,38)23(41,42)25(45,46)27(49,50)51)15-7-5-13(57-15)11-3-1-9(55-11)10-2-4-12(56-10)14-6-8-16(58-14)18(31,32)20(35,36)22(39,40)24(43,44)26(47,48)28(52,53)54/h1-8H

InChI key

UBMTYFFPSPVBSP-UHFFFAOYSA-N

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1 of 4

This Item
Z509353Z509337Z509345
Weighing funnel size XL, anti-static PP

Z509361

Weighing funnel

Weighing funnel size L, anti-static PP

Z509353

Weighing funnel

Weighing funnel size S, anti-static PP

Z509337

Weighing funnel

Weighing funnel size M, anti-static PP

Z509345

Weighing funnel

packaging

pkg of 10 ea

packaging

pkg of 20 ea

packaging

pkg of 50 ea

packaging

pkg of 50 ea

material

anti-static PP

material

anti-static PP

material

anti-static PP

material

anti-static PP

size

XL

size

L

size

S

size

M

General description

5,5′′′-Bis(tridecafluorohexyl)-2,2′:5′,2′′:5′′,2′′′-quaterthiophene (DFH-4T) is a n-type semiconducting material. It is a quaterthiophene derivative that contains fluoroalkyl groups and can be used as an electron transporting layer. It can be used in organic electronics.[1][2]

Application

This molecule has shown high mobilities (electron mobilities of up to 0.64 cm2/Vs) when used as an n-type semiconducting material in OFET devices.[3]

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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    Electronic effects of bis (2-aryl-4, 5, 6, 7-tetrahydroindenyl) titanocene dichlorides on the catalytic epoxidation of trans-3-hexene.
    Halterman RL and Ramsey TM.
    Journal of Organometallic Chemistry, 465(1), 175-179 (1994)
    Synthesis and ene reactions of di-(-)-menthyl diazenedicarboxylate.
    Brimble MA, et al.
    Tetrahedron Asymmetry, 7(7), 2007-2016 (1996)
    Study on the separation of 1-hexene and trans-3-hexene using ionic liquids.
    Jiqin Z, et al.
    Fluid Phase Equilibria, 247(1), 102-106 (2006)
    Oligomers from the ozonolyses of cis-and trans-3-hexene and cis-and trans-2, 5-dimethyl-3-hexene
    Murray RW and Su JS.
    The Journal of Organic Chemistry, 48(6), 817-822 (1983)
    Alla Zelenyuk et al.
    Faraday discussions, 200, 143-164 (2017-06-06)
    When secondary organic aerosol (SOA) particles are formed by ozonolysis in the presence of gas-phase polycyclic aromatic hydrocarbons (PAHs), their formation and properties are significantly different from SOA particles formed without PAHs. For all SOA precursors and all PAHs, discussed
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