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798746

Sigma-Aldrich

Exo-4-anisole Kwon [2.2.1] bicyclic phosphine

Synonym(s):

Exo-4-Methoxyphenyl Kwon [2.2.1] Bicyclic Phosphine, (1S,4S,5R)-5-(4-methoxyphenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane

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About This Item

Empirical Formula (Hill Notation):
C19H22NO3PS
Molecular Weight:
375.42
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Pricing and availability is not currently available.

form

powder

Quality Level

mp

85-90 °C

functional group

phosphine
sulfonamide

SMILES string

O=S(N1C[C@@]2([H])[P@](C3=CC=C(OC)C=C3)C[C@]1([H])C2)(C4=CC=C(C)C=C4)=O

InChI

1S/C19H22NO3PS/c1-14-3-9-19(10-4-14)25(21,22)20-12-18-11-15(20)13-24(18)17-7-5-16(23-2)6-8-17/h3-10,15,18H,11-13H2,1-2H3/t15-,18-,24?/m0/s1

InChI key

RMFZMNUGIFSNIE-YPAHSFBSSA-N

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1 of 4

This Item
HPA044345HPA024046HPA024503
conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

biological source

rabbit

biological source

rabbit

biological source

rabbit

biological source

rabbit

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

product line

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Prestige Antibodies® Powered by Atlas Antibodies

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Prestige Antibodies® Powered by Atlas Antibodies

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Prestige Antibodies® Powered by Atlas Antibodies

Gene Information

human ... TCTEX1D1(200132)

Gene Information

human ... ARRDC1(92714)

Gene Information

human ... OTUD6B(51633)

Gene Information

human ... OTUD6B(51633)

Application

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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