900275

(t-Bu)PhCPhos

95%

• Synonym(s): 2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl
• Empirical Formula (Hill Notation): C₂₆H₃₃N₂P
• CAS Number: 1660153-91-2
• Molecular Weight: 404.53
• MDL number: MFCD29905429
• UNSPSC Code: 12352200
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• form: powder or crystals
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• mp: 112 °C
• functional group: phosphine
• SMILES string: P(C(C)(C)C)(c2c(cccc2)c3c(cccc3N(C)C)N(C)C)c1ccccc1
• InChI: 1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3
• InChI key: HTHOMNNVAUPLKK-UHFFFAOYSA-N

Description

Application

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H413
• pcodes: P273 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable