901165
trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
≥95%
Synonym(s):
trans-(PCy3)2Ni(o-tolyl)Cl
Sign Into View Organizational & Contract Pricing
All Photos(2)
About This Item
Empirical Formula (Hill Notation):
C43H73ClNiP2
CAS Number:
Molecular Weight:
746.13
UNSPSC Code:
12352200
Recommended Products
![[(TMEDA)Ni(o-tolyl)Cl] 95%](/deepweb/assets/sigmaaldrich/product/structures/236/439/768c916e-994f-47e3-a980-3ca0471317d7/640/768c916e-994f-47e3-a980-3ca0471317d7.png)
nickel(II) chloride](/deepweb/assets/sigmaaldrich/product/structures/252/197/3c560697-beb3-4c52-85d6-ebc3af13db69/640/3c560697-beb3-4c52-85d6-ebc3af13db69.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II) 97%](/deepweb/assets/sigmaaldrich/product/structures/274/566/a60d6584-163a-4c41-a738-60f8e4d524fa/640/a60d6584-163a-4c41-a738-60f8e4d524fa.png)
![[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II) ≥95%](/deepweb/assets/sigmaaldrich/product/structures/175/664/fd7be2da-75c5-41f3-a430-8cf12a4cc144/640/fd7be2da-75c5-41f3-a430-8cf12a4cc144.png)
assay
≥95%
form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni](C1=C(C)C=CC=C1)(P(C2CCCCC2)(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)(C6CCCCC6)C7CCCCC7
Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
related product
Product No.
Description
Pricing
Storage Class
4.1B - Flammable solid hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Choose from one of the most recent versions:
Certificates of Analysis (COA)
Lot/Batch Number
Don't see the Right Version?
If you require a particular version, you can look up a specific certificate by the Lot or Batch number.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service