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M100005

Sigma-Aldrich

Myrcene

technical grade

Synonym(s):

β-Myrcene, 7-Methyl-3-methylene-1,6-octadiene

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About This Item

Linear Formula:
H2C=CHC(=CH2)CH2CH2CH=C(CH3)2
CAS Number:
123-35-3
Molecular Weight:
136.23
Beilstein/REAXYS Number:
1719990
EC Number:
204-622-5
MDL number:
MFCD00008908
UNSPSC Code:
12352100
PubChem Substance ID:
24896464
NACRES:
NA.22

grade

technical grade

Quality Level

200

vapor density

4.7 (vs air)

vapor pressure

~7 mmHg ( 20 °C)

contains

0.1% alpha-tocopherol

refractive index

n20/D 1.469 (lit.)

bp

167 °C (lit.)

solubility

water: soluble 0.00109 g/L at 20 °C

density

0.791 g/mL at 25 °C (lit.)

storage temp.

−20°C

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General description

Myrcene is a monoterpene. Males of Ips spp. produced the pheromones ipsdienol (2-methyl-6-methylene-2,7-octadien-4-ol) and/or ipsenol (2-methyl-6-methylene-7-octen-4-ol) on exposure to the vapours of myrcene. Myrcene serves as a precursor for terpene alcohols. Myrcene is a constituent of the beetle′s host, ponderosapine. Hydrogenation of myrcene catalyzed by Ru, Cr, Ir and Rh complexes yields a complex mixture of mono-, di- and trihydrogenated products.

Application

Myrcene is the suitable synthetic standard used in the identification of E-myrcenol (2-methyl-6-methylene-E-2,7-octadien-1-01) as a major hindgut constituent in Eurasian bark beetle Ips duplicatus by GC-MS.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

111.2 °F - closed cup

flash_point_c

44 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD2054
BCCC2662
BCBV9226
BCCB4872
BCBW6706

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Myrcene: a precursor of pheromones in Ips beetles.
P R Hughes
Journal of insect physiology, 20(7), 1274-1275 (1974-07-01)
E-myrcenol inIps duplicatus: An aggregation pheromone component new for bark beetles.
Byers JA, et al.
Experientia, 46(11-12), 1209-1211 (1990)
Selective hydrogenation of myrcene catalyzed by complexes of ruthenium, chromium, iridium and rhodium.
Speziali MG, et al.
J. Mol. Catal. A: Chem., 239(1), 10-14 (2005)
W D Bedard et al.
Science (New York, N.Y.), 164(3885), 1284-1285 (1969-06-13)
In the field, both sexes of the western pine beetle, Dendroctonus brevicomis, are attracted by the female-produced bicyclic ketal exo-brevicomin; this response is enhanced by myrcene (a constituent of the beetle's host, ponderosapine), which is not an attractant by itself.
Flavia Bonamin et al.
Chemico-biological interactions, 212, 11-19 (2014-02-01)
The monoterpene β-myrcene has been widely used in cosmetics, food and beverages, and it is normally found in essential oil from citrus fruit. The aim of this study was to investigate the anti-ulcer effects of β-myrcene on experimental models of
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