About This Item
Recommended Products
vapor pressure
233 hPa ( 20 °C)
Quality Level
form
liquid
reaction suitability
reagent type: oxidant
kinematic viscosity
0.314 cSt(20 °C)
bp
58.8 °C/1013 hPa
mp
-7.3 °C
solubility
35 g/L
density
3.12 g/cm3 at 20 °C (liquid)
storage temp.
15-25°C
Related Categories
1 of 4
This Item | 470864 | 1.01947 | 1.01945 |
|---|---|---|---|
| solubility 35 g/L | solubility - | solubility 35 g/L | solubility 35 g/L |
| reaction suitability reagent type: oxidant | reaction suitability - | reaction suitability - | reaction suitability - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| density 3.12 g/cm3 at 20 °C (liquid) | density 3.119 g/mL at 25 °C (lit.) | density 3.12 g/cm3 at 20 °C (liquid) | density 3.12 g/cm3 at 20 °C (liquid) |
| form liquid | form - | form liquid | form liquid |
| bp 58.8 °C/1013 hPa | bp 58.8 °C (lit.) | bp 58.8 °C/1013 hPa | bp 58.8 °C/1013 hPa |
General description
Application
- Primary alcohols to either aldehydes or esters and secondary alcohols to give ketones.[1]
- Alcohols or diols to tetrahydrofurans in the presence of silver(I) salts.[1]
- Enediol bis-trimethylsilyl ethers to α-diketones.[1]
- Aldehydes to esters in the presence of alcohol solvents and sodium bicarbonate buffer.[2]
- Aliphatic and aromatic thiols to disulfides.[3]
Bromine can also be used along with other co-reactants such as hexamethylphosphoric triamide (HMPA) and bis(tributyltin) oxide (HBD) to selectively oxidize secondary alcohols. However, bromine/nickel carboxylates convert 1,4-diols to γ-butyrolactones by selective oxidation of the primary alcohols.[1]
Analysis Note
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A
Storage Class
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk_germany
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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