310700

Manganese(IV) oxide

10 μm, reagent grade, ≥90%

• Synonym(s): Manganese dioxide
• Empirical Formula (Hill Notation): MnO₂
• CAS Number: 1313-13-9
• Molecular Weight: 86.94
• EC Number: 215-202-6
• MDL number: MFCD00003463
• UNSPSC Code: 12352303
• PubChem Substance ID: 329753639
• NACRES: NA.55
• assay: ≥90%
• grade: reagent grade
• form: powder

Properties

• grade: reagent grade
• Quality Level: 200
• assay: ≥90%
• form: powder
• particle size: 10 μm
• mp: 535 °C (dec.) (lit.)
• SMILES string: O=[Mn]=O
• InChI: 1S/Mn.2O
• InChI key: NUJOXMJBOLGQSY-UHFFFAOYSA-N

Description

General description

Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions.

Application

• High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018).



• Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).

Safety Information

• pictograms: GHS08,GHS07
• signalword: Warning
• hcodes: H302 + H332,H373
• pcodes: P260 - P264 - P271 - P301 + P312 - P304 + P340 + P312 - P314
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation
• target_organs: Brain
• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 2
• flash_point_f: does not flash
• flash_point_c: does not flash