38270

Diisopropyl ether

puriss. p.a., ≥98.5% (GC)

• Synonym(s): Isopropyl ether
• Linear Formula: (CH₃)₂CHOCH(CH₃)₂
• CAS Number: 108-20-3
• Molecular Weight: 102.17
• Beilstein/REAXYS Number: 1731256
• EC Number: 203-560-6
• MDL number: MFCD00008880
• UNSPSC Code: 12191502
• PubChem Substance ID: 329755758
• NACRES: NA.07
• assay: ≥98.5% (GC)
• technique(s): GC/GC: suitable
• bp: 68-69 °C (lit.)
• vapor pressure: 120 mmHg ( 20 °C)

Properties

• vapor density: 3.5 (vs air)
• Quality Level: 200
• vapor pressure: 120 mmHg ( 20 °C)
• grade: puriss. p.a.
• assay: ≥98.5% (GC)
• form: liquid
• autoignition temp.: 827 °F
• contains: ~0.001% 2,6-di-tert-butyl-4-methylphenol as stabilizer
• expl. lim.: 1-21 %, 100 °F
• technique(s): GC/GC: suitable
• impurities: ≤0.001% peroxides (as H₂O₂); ≤0.005% free acid (as C₂H₅COOH); ≤0.1% water; ≤0.5% isopropanol (GC)
• evapn. residue: ≤0.002%
• refractive index: n20/D 1.367 (lit.); n20/D 1.368
• bp: 68-69 °C (lit.)
• mp: −85 °C (lit.)
• density: 0.724 g/mL at 20 °C; 0.725 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 mg/kg; Ba: ≤0.1 mg/kg; Bi: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.1 mg/kg; K: ≤0.5 mg/kg; Li: ≤0.1 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Mo: ≤0.1 mg/kg; Na: ≤0.5 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.1 mg/kg; Sr: ≤0.1 mg/kg; Zn: ≤0.1 mg/kg
• SMILES string: CC(C)OC(C)C
• InChI: 1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3
• InChI key: ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

Description

General description

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent. Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed.

Application

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.

Safety Information

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H336
• pcodes: P210 - P233 - P240 - P241 - P242 - P243
• Hazard Classifications: Flam. Liq. 2 - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019,EUH066
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: -20.2 °F - closed cup
• flash_point_c: -29 °C - closed cup