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373710

Sigma-Aldrich

Molybdenum(VI) dichloride dioxide

Synonym(s):

Dichlorodioxomolybdenum

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100 ML
₩164,532

₩164,532


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100 ML
₩164,532

About This Item

Linear Formula:
MoO2Cl2
CAS Number:
Molecular Weight:
198.84
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Form:
flakes

₩164,532


Please contact Customer Service for Availability

Request a Bulk Order
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form

flakes

Quality Level

reaction suitability

core: molybdenum

concentration

34.4-36.9% chloride (silver nitrate titration)

density

3.31 g/mL at 25 °C (lit.)

SMILES string

Cl[Mo](Cl)(=O)=O

InChI

1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2

InChI key

JCFNAADCQWXIJD-UHFFFAOYSA-L

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This Item
RAB0060RAB0066RAB0062
species reactivity

human

species reactivity

human

species reactivity

human

species reactivity

human

Gene Information

human ... CCL22(6367)

Gene Information

human ... CCL20(6364)

Gene Information

human ... CCL24(6369)

Gene Information

human ... CCL21(6366)

assay range

inter-assay cv: <12%
intra-assay cv: <10%
sensitivity: 1.5 pg/mL
standard curve range: 1.65-400 pg/mL

assay range

inter-assay cv: <12%
intra-assay cv: <10%
sensitivity: 1.5 pg/mL
standard curve range: 0.8-600 pg/mL

assay range

inter-assay cv: <12%
intra-assay cv: <10%
sensitivity: 2 pg/mL
standard curve range: 1.37-1000 pg/mL

assay range

inter-assay cv: <12%
intra-assay cv: <10%
sensitivity: 30 pg/mL
standard curve range: 32.76-8000 pg/mL

input

sample type cell culture supernatant(s)
sample type urine
sample type plasma
sample type serum

input

sample type tissue lysate
sample type cell lysate

input

sample type plasma
sample type serum
sample type cell culture supernatant(s)
sample type urine

input

sample type plasma
sample type serum
sample type cell culture supernatant(s)
sample type urine

technique(s)

ELISA: suitable, capture ELISA: suitable

technique(s)

ELISA: suitable, capture ELISA: suitable

technique(s)

ELISA: suitable, capture ELISA: suitable

technique(s)

ELISA: suitable, capture ELISA: suitable

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

General description

Molybdenum(VI) dichloride dioxide is an oxo-halide of molybdenum widely used as a catalyst for various organic transformations. It is an oxo-transfer catalyst that has the ability to promote oxidation as well as reduction reactions. It can also be used as a chemical vapor deposition(CVD) precursor to synthesize various Mo-based nanomaterials.[1] [2]

Application

[3]Molybdenum(VI) dichloride dioxide can be used as a catalyst:
  • For thioacetalization of heterocyclic, aromatic, and aliphatic compounds.[1]
  • To synthesize mono-, di-, tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates.[4]
  • For stereospecific deoxygenation of epoxides to alkenes.[5]
  • For the synthesis of dihydropyrimidinone/thione and polyhydroquinoline derivatives via a Biginelli and Hantzsch reaction.[3]
It can also be used as a precursor to synthesize MoO2 nanoparticles.[2]

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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