676578

Bis(tri-tert-butylphosphine)palladium(0)

• Synonyme(s) : Pd(t-Bu₃P)₂
• Formule empirique (notation de Hill) : C₂₄H₅₄P₂Pd
• CAS Number: 53199-31-8
• Poids moléculaire : 511.05
• Numéro MDL: MFCD03094580
• Code UNSPSC : 12161600
• ID de substance PubChem : 24884857
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solid
• Niveau de qualité: 100
• Pertinence de la réaction: core: palladium; reagent type: catalyst
• Capacité de réaction: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 258-272 °C
• Autre catégorie plus écologique: , Aligned
• Température de stockage: −20°C
• Chaîne SMILES: [Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
• Clé InChI: MXQOYLRVSVOCQT-UHFFFAOYSA-N

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

• Catalyst for Suzuki coupling on a multisubstituted sp³-carbon (eq. 1)
• Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
• Catalyst for Negishi coupling reaction (eq. 3)
• Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
• Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
• Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)

Catalyst for greener Heck reaction in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable