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377384

Sigma-Aldrich

Tetraamminepalladium(II) nitrate solution

10 wt. % in H2O

Synonym(s):

Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate

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10 MG
₩211,019
50 MG
₩848,439

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10 MG
₩211,019
50 MG
₩848,439

About This Item

Linear Formula:
Pd(NH3)4(NO3)2
CAS Number:
13601-08-6
Molecular Weight:
298.55
MDL number:
MFCD00011591
UNSPSC Code:
12161600
PubChem Substance ID:
24863500
NACRES:
NA.22

₩211,019

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form

liquid

Quality Level

100

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

concentration

10 wt. % in H2O

refractive index

n20/D 1.348

density

1.04 g/mL at 25 °C

SMILES string

N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

WIDMMNCAAAYGKW-UHFFFAOYSA-N

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1 of 4

This Item
PHR1893Y00020201724827
Zoledronic acid monohydrate ≥98% (HPLC)

SML0223

Zoledronic acid monohydrate

Zoledronic Acid Pharmaceutical Secondary Standard; Certified Reference Material

PHR1893

Zoledronic Acid

Zoledronic acid monohydrate European Pharmacopoeia (EP) Reference Standard

Y0002020

Zoledronic acid monohydrate

Zoledronic acid United States Pharmacopeia (USP) Reference Standard

1724827

Zoledronic acid

form

powder

form

powder

form

-

form

-

assay

≥98% (HPLC)

assay

-

assay

-

assay

-

Quality Level

100

Quality Level

300

Quality Level

-

Quality Level

-

storage temp.

2-8°C

storage temp.

2-30°C

storage temp.

2-8°C

storage temp.

-

solubility

H2O: ≥2 mg/mL

solubility

-

solubility

-

solubility

-

storage condition

desiccated, protect from light

storage condition

-

storage condition

-

storage condition

-

Application

Precursor to heterogeneous platinum catalysts for isomerizing unfunctionalized alkanes.[1]
Used to prepare a Pd/TS-1 catalyst for the in situ generation of H2O2 and subsequent oxidation of propylene to propylene oxide.[2]

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H272,H315,H319

Hazard Classifications

Eye Irrit. 2 - Ox. Liq. 2 - Skin Irrit. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN0534
MKCJ5343
MKCB2640V
13119CJ
12424MH

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Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
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