223670

Bis(cyclopentadienyl)zirconium(IV) chloride hydride

95%

• 동의어(들): Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride
• 실험식(Hill 표기법): C₁₀H₁₁ClZr
• CAS Number: 37342-97-5
• Molecular Weight: 257.87
• EC Number: 253-479-5
• MDL number: MFCD02089401
• UNSPSC 코드: 12352101
• PubChem Substance ID: 24853395
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 양식: powder
• 반응 적합성: core: zirconium; reagent type: catalyst; reagent type: reductant
• SMILES string: [H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
• InChI key: PSYHEBZUPSHSKK-UHFFFAOYSA-M

설명

일반 설명

Bis(cyclopentadienyl)zirconium(IV) chloride hydride, also known as Schwartz′s reagent, is utilized as a catalyst in in olefin polymerization.

애플리케이션

Bis(cyclopentadienyl)zirconium(IV) chloride hydride can be used:

• To convert amides to aldehydes.
• As a reagent for the functionalization of olefins and alkynes.
• As a reducing agent in the preparation of (E)-vinyl organochalcogenides.
• To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.

안전성 정보

• 픽토그램: GHS02,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H261,H314
• 예방조치 성명서: P223 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Skin Corr. 1B - Water-react 2
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges