256269

(S,S)-(−)-Hydrobenzoin

99%, optical purity ee: 99% (GLC)

• 동의어(들): (S,S)-(−)-1,2-Diphenyl-1,2-ethanediol, (S,S)-1,2-Diphenylethylene glycol
• Linear Formula: C₆H₅CH(OH)CH(OH)C₆H₅
• CAS Number: 2325-10-2
• Molecular Weight: 214.26
• Beilstein: 2330888
• MDL number: MFCD00064255
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24855513
• NACRES: NA.22

속성

• 분석: 99%
• 광학 활성: [α]24/D −94°, c = 2.5 in ethanol
• 광학 순도: ee: 99% (GLC)
• mp: 148-150 °C (lit.)
• 작용기: hydroxyl; phenyl
• SMILES string: O[C@H]([C@@H](O)c1ccccc1)c2ccccc2
• InChI: 1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m0/s1
• InChI key: IHPDTPWNFBQHEB-KBPBESRZSA-N

설명

일반 설명

Chiral reagent.

애플리케이션

(S,S)-(-)-Hydrobenzoin may also be used to prepare (1S,2S,1′S)- and (1S,2S,1′R)-2-(cyclohex-2′-enyloxy)-1,2-diphenylethanol, which are intermediates to prepare enantiopure cyclohexitols. The (S,S)-(-)-hydrobenzoin/Ca complex may be used to catalyze the direct asymmetric aldol reaction of acetophenone and pivalaldehyde to form (R)-3-hydroxy-4,4-dimethyl-1-phenylpentan-1-one.

C₂ symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)