377155

Chlorobis(cyclooctene)iridium(I)dimer

97%

• 동의어(들): [Ir(coe)₂Cl]₂, Di-μ-chlorotetrakis(cyclooctene)diiridium
• 실험식(Hill 표기법): C₃₂H₅₆Cl₂Ir₂
• CAS Number: 12246-51-4
• Molecular Weight: 896.13
• MDL number: MFCD00213465
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24863496
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: powder
• 반응 적합성: core: iridium; reagent type: catalyst
• mp: 160-165 °C (dec.) (lit.)
• SMILES string: Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
• InChI: 1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
• InChI key: WBRREXQCZAFSKS-XFCUKONHSA-L

설명

애플리케이션

Catalyst for:

• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
• Alkylation reactions
• Guerbet reaction
• Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
• Asymmetric hydroamination reactions

Chlorobis(cyclooctene)iridium(I)dimer can be used as a catalyst for:

• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.
• Alkylation reactions.
• Guerbet reaction.
• Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.
• Asymmetric hydroamination reactions.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves