685062

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

• 동의어(들): [Ir(OMe)(1,5-cod)]₂, Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
• Linear Formula: [Ir(OCH₃)(C₈H₁₂)]₂
• CAS Number: 12148-71-9
• Molecular Weight: 662.86
• MDL number: MFCD08459360
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329760940
• NACRES: NA.22

속성

• 양식: crystals
• Quality Level: 100
• 반응 적합성: core: iridium; reagent type: catalyst; reaction type: C-H Activation
• mp: 154-179 °C (D)
• 저장 온도: −20°C
• SMILES string: C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4
• InChI: 1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;
• InChI key: BGWIAAATAAWGOI-MIXQCLKLSA-N

설명

애플리케이션

A powerful C-H activation catalyst to prepare phenols from arenes

Catalyst for:

• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase
• Borylation/Suzuki-Miyaura coupling
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls
• Tetraborylation reactions
• Highly regio- and enantioselective asymmetric hydroboration
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves