385638

Di-(2-picolyl)amine

97%

• 동의어(들): Bis(2-pyridylmethyl)amine
• 실험식(Hill 표기법): C₁₂H₁₃N₃
• CAS Number: 1539-42-0
• Molecular Weight: 199.25
• EC Number: 216-266-8
• MDL number: MFCD00129044
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24864040
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• refractive index: n20/D 1.578 (lit.)
• bp: 139-141 °C/1 mmHg (lit.)
• solubility: water: soluble (partially miscible)(lit.)
• density: 1.107 g/mL at 25 °C (lit.)
• 작용기: amine
• SMILES string: C(NCc1ccccn1)c2ccccn2
• InChI: 1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
• InChI key: KXZQYLBVMZGIKC-UHFFFAOYSA-N

설명

일반 설명

Di-(2-picolyl)amine (DPA), a secondary amine containing two picolyl substituents, acts as a tridentate ligand due to its three donor nitrogen atoms. It is commonly used in coordination chemistry for the synthesis of binary, ternary, and binuclear complexes with various metal ions, including copper (Cu) and cadmium (Cd).

애플리케이션

Di-(2-picolyl)amine can be used as:

• A reactant to synthesize di(2-pyridylmethylamino)alkanoic esters using ω-iodoaliphatic carboxylic esters in the presence of triethylamine.
• A ligand to synthesize iron complexes of di-(2-picolyl)amine by treating with iron trichloride, which can be used to catalyze the direct hydroxylation of benzene to phenol.
• A reagent for the protection of carboxylic acids as carboxamides of bispicolylamine.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter