720526

Palladium(π-cinnamyl) chloride dimer

97%

• 동의어(들): Bis[cinnamyl palladium(II) chloride], Palladium(1-phenylallyl)chloride dimer, [(Cinnamyl)PdCl]₂, [Pd(1-phenylallyl)Cl]₂
• 실험식(Hill 표기법): C₁₈H₁₈Cl₂Pd₂
• CAS Number: 12131-44-1
• Molecular Weight: 518.08
• MDL number: MFCD16621470
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329763720
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 218-220 °C
• 저장 온도: 2-8°C
• SMILES string: Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2
• InChI: 1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: SHWAPUDBEQXXLQ-UHFFFAOYSA-L

설명

애플리케이션

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:

• Ammonia cross-coupling reactions to synthesize arylamines.
• Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable