922722

O-Pivaloylhydroxyamine triflic acid

• 동의어(들): 2,2-dimethyl-, azanyl ester, 1,1,1-trifluoromethanesulfonate, PivONH₃OTF, Propanoic acid
• 실험식(Hill 표기법): C₅H₁₁NO₂ · CHF₃O₃S
• CAS Number: 1293990-73-4
• Molecular Weight: 267.22
• MDL number: MFCD32701977
• UNSPSC 코드: 12352106
• NACRES: NA.22

속성

• 양식: solid
• Quality Level: 100
• 작용기: fluoro; triflate
• SMILES string: FC(F)(F)[S](=O)(=O)[O-].[N+H3]OC(=O)C(C)(C)C
• InChI key: AJUKGKFBUGZGSW-UHFFFAOYSA-M

설명

애플리케이션

This hydroxylamine-based reagent enables the iron-catalyzed selective transformation of thiols to sulfinamides under mild conditions without the use of precious metal catalysts or additional oxidants. This reagent is shelf stable and facilitates the reaction in a single step and under mild conditions.

기타 정보

Hydroxylamine-Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron Catalyzed Preparation of Unprotected Sulfinamides from Thiols

Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H302,H314,H335
• 예방조치 성명서: P260 - P271 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable