405426

2,6-Bis(bromomethyl)pyridine

98%

• Synonym(s): α,α′-Dibromo-2,6-lutidine, 1,6-Bis(bromomethyl)pyridine, 2,6-Di(bromomethyl)pyridine
• Empirical Formula (Hill Notation): C₇H₇Br₂N
• CAS Number: 7703-74-4
• Molecular Weight: 264.95
• MDL number: MFCD00191795
• UNSPSC Code: 12352100
• PubChem Substance ID: 24865316
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 98%
• mp: 85-87 °C (lit.)
• functional group: bromo
• SMILES string: BrCc1cccc(CBr)n1
• InChI: 1S/C7H7Br2N/c8-4-6-2-1-3-7(5-9)10-6/h1-3H,4-5H2
• InChI key: QUTSYCOAZVHGGT-UHFFFAOYSA-N

Description

General description

Crystal of 2,6-bis(bromomethyl)pyridine has the molecules related by a c-glide-plane operation. Molecules are arranged into stacks along the c axis. It participates in the synthesis of dicationic imidazolium-linked cyclophane.

Application

2,6-Bis(bromomethyl)pyridine may be used in the preparation of the following:

• a new pyridine-pyrazole derivative, 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine
• a large macrocyclic ligand, N(1),N(7)-pyridine-2,6-dimethyl-N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide dibromide
• small-ring, potentially tridentate Se(2)N(pyridyl)-donor macrocycles

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H315,H319,H335
• pcodes: P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves