657336

1,3,5-Tris(bromomethyl)benzene

97%

• Synonym(s): 2,4,6-Tri(bromomethyl)benzene, Tribromomesitylene
• Linear Formula: C₉H₉Br₃
• CAS Number: 18226-42-1
• Molecular Weight: 356.88
• MDL number: MFCD00182500
• UNSPSC Code: 12352103
• PubChem Substance ID: 24884279
• NACRES: NA.23

Properties

• Quality Level: 100
• assay: 97%
• form: solid
• mp: 94-99 °C
• SMILES string: BrCc1cc(CBr)cc(CBr)c1
• InChI: 1S/C9H9Br3/c10-4-7-1-8(5-11)3-9(2-7)6-12/h1-3H,4-6H2
• InChI key: GHITVUOBZBZMND-UHFFFAOYSA-N

Description

General description

1,3,5-Tris(bromomethyl)benzene has three bromo substituents around an aromatic ring that can be used as a cross-linker. It is mainly utilized in the synthesis of ligands and dendrimeric monomers.

Application

1,3,5-Tris(bromomethyl)benzene can be crosslinked with triptycene monomers by using Friedel-Crafts alkylation reaction to form microporous polymers for selective adsorption of CO₂ and H₂. Proton exchange membranes (PEMs) can be fabricated by covalently linking polybenzimidazole (PBI) and 1,3,5-tris(bromomethyl)benzene as part of the tri-functional bromomethyls for fuel cell applications. It is also used in the synthesis of trifluoroacetamide derivative triaza[3₃]cyclophane.

A monomer for synthesizing dendrimers and light emitting oligomers.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges