719439

XtalFluor-E^®

• 동의어(들): DAST difluorosulfinium salt, (Diethylamino)difluorosulfonium tetrafluoroborate, N,N-Diethyl-S,S-difluorosulfiliminium tetrafluoroborate, N,N-Diethylamino-S,S-difluorosulfinium tetrafluoroborate, N-(Difluoro-λ₄-sulfanylidene)-N-ethyl-ethanaminium tetrafluoroborate
• 실험식(Hill 표기법): C₄H₁₀BF₆NS
• CAS Number: 63517-29-3
• Molecular Weight: 229.00
• MDL number: MFCD15144877
• UNSPSC 코드: 12352101
• PubChem Substance ID: 329763649
• NACRES: NA.22

속성

• 양식: solid
• Quality Level: 100
• mp: 84-87 °C
• 작용기: amine
• 저장 온도: −20°C
• SMILES string: F[B-](F)(F)F.CC\[N+](CC)=S(\F)F
• InChI: 1S/C4H10F2NS.BF4/c1-3-7(4-2)8(5)6;2-1(3,4)5/h3-4H2,1-2H3;/q+1;-1
• InChI key: YLNKFQWRRIXZPJ-UHFFFAOYSA-N

설명

일반 설명

XtalFluor-E^® is widely used in formylation, ring expansion, proto-functionalization, cyclodehydration, and dehydration.

애플리케이션

Convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scope

Deoxofluorination reagent with a better safety profile, that doesn′t generate corrosive HF which makes it suitable for use in standard borosilicate vessels, and does not react violently with water

Reactant for:

• Preparation of fluorodisaccharides

Triisopropylsilanethiol was recently reported by MacMillian and coworkers to be used as an organocatalyst, in tandem with Ir(III) specifically Aldrich product 688096, in photoredox catalysis. This approach directly couples a cyano-containing arene with an allylic sp³ C-H bond.

기타 정보

The direct arylation of allylic sp³ C–H bonds via organic and photoredox catalysis

법적 정보

XtalFluor-E is a registered trademark of OmegaChem, Inc.

안전성 정보

• 픽토그램: GHS06,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H311 + H331,H314
• 예방조치 성명서: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B
• 보충제 위험성: EUH014
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable