763284

9-Azabicyclo[3.3.1]nonane N-oxyl

95%

• 동의어(들): 9-Azabicyclo[3.3.1]nonane N-oxyl radical, ABNO
• 실험식(Hill 표기법): C₈H₁₄NO
• CAS Number: 31785-68-9
• Molecular Weight: 140.20
• Beilstein: 1681761
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329767041
• NACRES: NA.22

속성

• 분석: 95%
• 양식: solid
• 반응 적합성: reagent type: ligand
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 65-70 °C
• 환경친화적 대안 카테고리: , Aligned
• 저장 온도: 2-8°C
• SMILES string: C[C@@]12CCC[C@@](C)(CCC1)N2[O]
• InChI: 1S/C10H18NO/c1-9-5-3-7-10(2,11(9)12)8-4-6-9/h3-8H2,1-2H3/t9-,10+
• InChI key: GGWCZKZSILYISB-AOOOYVTPSA-N

설명

일반 설명

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) belongs to a sterically unhindered and stable class of nitroxyl radicals. It efficiently catalyzes the oxidation of alcohols to afford the corresponding carbonyl compounds. ABNO along with (^MeObpy)Cu^I(OTf) (^MeObpy =4,4′-dimethoxy-2,2′-bipyridine) comprises a catalytic system. This catalytic system is useful for the aerobic oxidation of all categories of alcohols.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) may be employed for the aerobic oxidation of alcohols.

Catalytic oxidant for copper-catalyzed greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H302,H318
• 예방조치 성명서: P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable